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Photochemical Carboxylation of Activated C(sp 3 )−H Bonds with CO 2
Author(s) -
Gui YongYuan,
Zhou WenJun,
Ye JianHeng,
Yu DaGang
Publication year - 2017
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201700205
Subject(s) - carboxylation , allylic rearrangement , chemistry , photochemistry , amine gas treating , carbocation , organic chemistry , catalysis
From ugly duckling to beautiful C1 : Although CO 2 may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO 2 has mainly been confined to highly reactive species. However, recent significant breakthroughs have been made in photochemical carboxylation of challenging, un‐acidic, C(sp 3 )−H bonds, including benzylic, allylic and amine C−H bonds.
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