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Synthesis Optimization, Shaping, and Heat Reallocation Evaluation of the Hydrophilic Metal–Organic Framework MIL‐160(Al)
Author(s) -
Permyakova Anastasia,
Skrylnyk Oleksandr,
Courbon Emilie,
Affram Maame,
Wang Sujing,
Lee UHwang,
Valekar Anil H.,
Nouar Farid,
Mouchaham Georges,
Devic Thomas,
De Weireld Guy,
Chang JongSan,
Steunou Nathalie,
Frère Marc,
Serre Christian
Publication year - 2017
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201700164
Subject(s) - microporous material , pellets , materials science , porosity , sorption , metal organic framework , chemical engineering , energy storage , metal , nanotechnology , organic chemistry , adsorption , chemistry , composite material , metallurgy , thermodynamics , power (physics) , physics , engineering
The energy‐storage capacities of a series of water‐stable porous metal–organic frameworks, based on high‐valence metal cations (Al 3+ , Fe 3+ , Cr 3+ , Ti 4+ , Zr 4+ ) and polycarboxylate linkers, were evaluated under the typical conditions of seasonal energy‐storage devices. The results showed that the microporous hydrophilic Al‐dicarboxylate MIL‐160(Al) exhibited one of the best performances. To assess the properties of this material for space‐heating applications on a laboratory pilot scale with an open reactor, a new synthetic route involving safer, greener conditions was developed. This led to the production of MIL‐160(Al) on a 400 g scale, before the material was shaped into pellets through a wet‐granulation method. The material exhibited a very high energy‐storage capacity for a physical‐sorption material (343 Wh kg −1 ), which is in full agreement with the predicted value.