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Heterostructured WS 2 ‐MoS 2 Ultrathin Nanosheets Integrated on CdS Nanorods to Promote Charge Separation and Migration and Improve Solar‐Driven Photocatalytic Hydrogen Evolution
Author(s) -
Reddy D. Amaranatha,
Park Hanbit,
Ma Rory,
Kumar D. Praveen,
Lim Manho,
Kim Tae Kyu
Publication year - 2017
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201601799
Subject(s) - photocatalysis , nanorod , materials science , water splitting , noble metal , hydrogen production , catalysis , nanotechnology , hydrogen , nanocomposite , chemical engineering , photocatalytic water splitting , metal , chemistry , organic chemistry , engineering , metallurgy
Solar‐driven photocatalytic hydrogen evolution is important to bring solar‐energy‐to‐fuel energy‐conversion processes to reality. However, there is a lack of highly efficient, stable, and non‐precious photocatalysts, and catalysts not designed completely with expensive noble metals have remained elusive, which hampers their large‐scale industrial application. Herein, for the first time, a highly efficient and stable noble‐metal‐free CdS/WS 2 ‐MoS 2 nanocomposite was designed through a facile hydrothermal approach. When assessed as a photocatalyst for water splitting, the CdS/WS 2 ‐MoS 2 nanostructures exhibited remarkable photocatalytic hydrogen‐evolution performance and impressive durability. An excellent hydrogen evolution rate of 209.79 mmol g −1 h −1 was achieved under simulated sunlight irradiation, which is higher than the values for CdS/MoS 2 (123.31 mmol g −1 h −1 ) and CdS/WS 2 nanostructures (169.82 mmol g −1 h −1 ) and the expensive CdS/Pt benchmark catalyst (34.98 mmol g −1 h −1 ). The apparent quantum yield reached 51.4 % at λ =425 nm in 5 h. Furthermore, the obtained hydrogen evolution rate was better than those of several noble‐metal‐free catalysts reported previously. The observed high rate of hydrogen evolution and remarkable stability may be a result of the ultrafast separation of photogenerated charge carriers and transport between the CdS nanorods and the WS 2 ‐MoS 2 nanosheets, which thus increases the number of electrons involved in hydrogen production. The proposed designed strategy is believed to potentially open a door to the design of advanced noble‐metal‐free photocatalytic materials for efficient solar‐driven hydrogen production.