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High‐Capacity Layered‐Spinel Cathodes for Li‐Ion Batteries
Author(s) -
Nayak Prasant Kumar,
Levi Elena,
Grinblat Judith,
Levi Mikhael,
Markovsky Boris,
Munichandraiah N.,
Sun Yang Kook,
Aurbach Doron
Publication year - 2016
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201600576
Subject(s) - spinel , cathode , materials science , electrochemistry , cycling , chemical engineering , ion , oxide , capacity loss , nanotechnology , metallurgy , electrode , chemistry , archaeology , organic chemistry , engineering , history
Li and Mn‐rich layered oxides with the general structure x Li 2 MnO 3 ⋅(1– x ) LiMO 2 (M=Ni, Mn, Co) are promising cathode materials for Li‐ion batteries because of their high specific capacity, which may be greater than 250 mA h g −1 . However, these materials suffer from high first‐cycle irreversible capacity, gradual capacity fading, limited rate capability and discharge voltage decay upon cycling, which prevent their commercialization. The decrease in average discharge voltage is a major issue, which is ascribed to a structural layered‐to‐spinel transformation upon cycling of these oxide cathodes in wide potential ranges with an upper limit higher than 4.5 V and a lower limit below 3 V versus Li. By using four elements systems (Li, Mn, Ni, O) with appropriate stoichiometry, it is possible to prepare high capacity composite cathode materials that contain LiMn 1.5 Ni 0.5 O 4 and Li x Mn y Ni z O 2 components. The Li and Mn‐rich layered‐spinel cathode materials studied herein exhibit a high specific capacity (≥200 mA h g −1 ) with good capacity retention upon cycling in a wide potential domain (2.4–4.9 V). The effect of constituent phases on their electrochemical performance, such as specific capacity, cycling stability, average discharge voltage, and rate capability, are explored here. This family of materials can provide high specific capacity, high rate capability, and promising cycle life. Using Co‐free cathode materials is also an obvious advantage of these systems.