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Investigation of the Hydrogenation of 5‐Methylfurfural by Noble Metal Nanoparticles in a Microcapillary Reactor
Author(s) -
Gmeiner Julia,
Seibicke Max,
Behrens Silke,
Spliethoff Bernd,
Trapp Oliver
Publication year - 2016
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201600045
Subject(s) - selectivity , noble metal , catalysis , nanoparticle , chemistry , throughput , nanotechnology , polymer , materials science , organic chemistry , computer science , telecommunications , wireless
On‐column reaction gas chromatography (ocRGC) was successfully utilized as high‐throughput platform for monitoring of the conversion and selectivity of hydrogenation of 5‐methylfurfural catalyzed by polymer‐stabilized Ru and Pd nanoparticles. We were able to elucidate the effect of various reaction conditions, mainly together with the catalyst loading on the conversion rate and the selectivity of the reaction. Our strategy yields significant improvements in reaction analysis times and cost effectiveness in comparison to standard methods. We are able to demonstrate that ocRGC approach provides valuable information about the reaction system that gives scientists a tool to design suitable catalytic systems for enhanced sustainable chemistry in the future.