The Role of MgCl 2  as a Lewis Base in ROMgCl–MgCl 2  Electrolytes for Magnesium‐Ion Batteries | Zendy

Pan Baofei | Zendy; Huang Jinhua | Zendy; He Meinan | Zendy; Brombosz Scott M. | Zendy; Vaughey John T. | Zendy; Zhang Lu | Zendy; Burrell Anthony K. | Zendy; Zhang Zhengcheng | Zendy; Liao Chen | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The Role of MgCl 2 as a Lewis Base in ROMgCl–MgCl 2 Electrolytes for Magnesium‐Ion Batteries

Author(s) -

Pan Baofei,

Huang Jinhua,

He Meinan,

Brombosz Scott M.,

Vaughey John T.,

Zhang Lu,

Burrell Anthony K.,

Zhang Zhengcheng,

Liao Chen

Publication year - 2016

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201501557

Subject(s) - lewis acids and bases , chemistry , alkoxide , magnesium , electrolyte , inorganic chemistry , alkyl , crystallography , catalysis , organic chemistry , electrode

A series of strong Lewis acid‐free alkoxide/siloxide‐based Mg electrolytes were deliberately developed with remarkable oxidative stability up to 3.5 V (vs. Mg/Mg 2+ ). Despite the perception of ROMgCl (R=alkyl, silyl) as a strong base, ROMgCl acts like Lewis acid, whereas the role of MgCl 2 in was unambiguously demonstrated as a Lewis base through the identification of the key intermediate using single crystal X‐ray crystallography. This Lewis‐acid‐free strategy should provide a prototype system for further investigation of Mg‐ion batteries.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research