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Evaluation of Metal‐Organic Frameworks and Porous Polymer Networks for CO 2 ‐Capture Applications
Author(s) -
Verdegaal Wolfgang M.,
Wang Kecheng,
Sculley Julian P.,
Wriedt Mario,
Zhou HongCai
Publication year - 2016
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201501464
Subject(s) - metal organic framework , porosity , polymer , materials science , porous medium , chemical engineering , nanotechnology , chemistry , organic chemistry , adsorption , engineering , composite material
This manuscript presents experimental data for 20 adsorption materials (metal–organic frameworks, porous polymer networks, and Zeolite‐5A), including CO 2 and N 2 isotherms and heat capacities. With input from only experimental data, working capacities per energy for each material were calculated. Furthermore, by running seven different carbon‐capture scenarios in which the initial flue‐gas composition and process temperature was systematically changed, we present a range of performances for each material and quantify how sensitive each is to these varying parameters. The presented calculations provide researchers with a tool to investigate promising carbon‐capture materials more easily and completely.