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Recycled Poly(vinyl alcohol) Sponge for Carbon Encapsulation of Size‐Tunable Tin Dioxide Nanocrystalline Composites
Author(s) -
Ma Yue,
Tai CheukWai,
Gustafsson Torbjörn,
Edström Kristina
Publication year - 2015
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201500297
Subject(s) - vinyl alcohol , materials science , chemical engineering , anode , tin dioxide , tin oxide , electrolyte , tin , nanocrystalline material , composite number , oxide , composite material , nanotechnology , polymer , electrode , metallurgy , chemistry , engineering
The recycling of industrial materials could reduce their environmental impact and waste haulage fees and result in sustainable manufacturing. In this work, commercial poly(vinyl alcohol) (PVA) sponges are recycled into a macroporous carbon matrix to encapsulate size‐tunable SnO 2 nanocrystals as anode materials for lithium‐ion batteries (LIBs) through a scalable, flash‐combustion method. The hydroxyl groups present copiously in the recycled PVA sponges guarantee a uniform chemical coupling with a tin(IV) citrate complex through intermolecular hydrogen bonds. Then, a scalable, ultrafast combustion process (30 s) carbonizes the PVA sponge into a 3D carbon matrix. This PVA‐sponge‐derived carbon could not only buffer the volume fluctuations upon the Li–Sn alloying and dealloying processes but also afford a mixed conductive network, that is, a continuous carbon framework for electrical transport and macropores for facile electrolyte percolation. The best‐performing electrode based on this composite delivers a rate performance up to 9.72 C (4 A g −1 ) and long‐term cyclability (500 cycles) for Li + ion storage. Moreover, cyclic voltammograms demonstrate the coexistence of alloying and dealloying processes and non‐diffusion‐controlled pseudocapacitive behavior, which collectively contribute to the high‐rate Li + ion storage.