Fluorinated Alcohols as Activators for the Solvent‐Free Chemical Fixation of Carbon Dioxide into Epoxides | Zendy

Gennen Sandro | Zendy; Alves Margot | Zendy; Méreau Raphaël | Zendy; Tassaing Thierry | Zendy; Gilbert Bernard | Zendy; Detrembleur Christophe | Zendy; Jerome Christine | Zendy; Grignard Bruno | Zendy

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Fluorinated Alcohols as Activators for the Solvent‐Free Chemical Fixation of Carbon Dioxide into Epoxides

Author(s) -

Gennen Sandro,

Alves Margot,

Méreau Raphaël,

Tassaing Thierry,

Gilbert Bernard,

Detrembleur Christophe,

Jerome Christine,

Grignard Bruno

Publication year - 2015

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201500103

Subject(s) - chemistry , onium , carbon fixation , titration , solvent , organic chemistry , catalysis , green chemistry , ionic liquid , combinatorial chemistry , carbon dioxide , ion

The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO 2 into epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO 2 /epoxides coupling.

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