Direct Synthesis of 1,6‐Hexanediol from HMF over a Heterogeneous Pd/ZrP Catalyst using Formic Acid as Hydrogen Source | Zendy

Tuteja Jaya | Zendy; Choudhary Hemant | Zendy; Nishimura Shun | Zendy; Ebitani Kohki | Zendy

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Direct Synthesis of 1,6‐Hexanediol from HMF over a Heterogeneous Pd/ZrP Catalyst using Formic Acid as Hydrogen Source

Author(s) -

Tuteja Jaya,

Choudhary Hemant,

Nishimura Shun,

Ebitani Kohki

Publication year - 2014

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201300832

Subject(s) - chemistry , catalysis , formic acid , furan , yield (engineering) , lewis acids and bases , brønsted–lowry acid–base theory , hydrogen , ring (chemistry) , organic chemistry , zirconium phosphate , inorganic chemistry , phosphate , materials science , metallurgy

A new approach is developed for hydrogenolytic ring opening of biobased 5‐hydroxymethylfurfural (HMF), dehydration product of hexoses, towards 1,6‐hexanediol (HDO) under atmospheric pressure. The highest yield of HDO, 43 %, is achieved over reusable Pd/zirconium phosphate (ZrP) catalyst at 413 K in the presence of formic acid as hydrogen source. In comparison with various Brønsted and/or Lewis acidic supports, the specific Brønsted acidity on ZrP support effectively accelerated the cleavage of CO bond in a furan ring.

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