Synthesis of Pt–Cu Nanodendrites through Controlled Reduction Kinetics for Enhanced Methanol Electro‐Oxidation | Zendy

Taylor Eric | Zendy; Chen Shutang | Zendy; Tao Jing | Zendy; Wu Lijun | Zendy; Zhu Yimei | Zendy; Chen Jingyi | Zendy

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Synthesis of Pt–Cu Nanodendrites through Controlled Reduction Kinetics for Enhanced Methanol Electro‐Oxidation

Author(s) -

Taylor Eric,

Chen Shutang,

Tao Jing,

Wu Lijun,

Zhu Yimei,

Chen Jingyi

Publication year - 2013

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201300527

Subject(s) - methanol , coalescence (physics) , kinetics , nanotechnology , nanostructure , oxidation reduction , computer science , chemical engineering , combinatorial chemistry , chemistry , materials science , organic chemistry , physics , biochemistry , quantum mechanics , astrobiology , engineering

Final reductions: Alloyed Pt–Cu nanodendrites are synthesized through a two‐step co‐reduction method, in which the reduction rate is controlled by the oxidative etchants and the reducing agents. These dendritic nanostructures are the result of overgrowth along the <111> axis of the face‐centered cubic structure and the coalescence of small dendritic seeds. These nanodendrites are highly active for methanol electro‐oxidation because of their unique structure and the bifunctionality of Pt and Cu.

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