Premium
Dehydrogenation of Dodecahydro‐ N ‐ethylcarbazole on Pt(111)
Author(s) -
Gleichweit Christoph,
Amende Max,
Schernich Stefan,
Zhao Wei,
Lorenz Michael P. A.,
Höfert Oliver,
Brückner Nicole,
Wasserscheid Peter,
Libuda Jörg,
Steinrück HansPeter,
Papp Christian
Publication year - 2013
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201300263
Subject(s) - dehydrogenation , hydrogen storage , catalysis , hydrogen , molecule , materials science , boiling , organic chemistry , chemistry , chemical engineering , photochemistry , inorganic chemistry , engineering
Sloshing hydrogen: Liquid organic hydrogen carriers are high‐boiling organic molecules, which can be reversibly hydrogenated and dehydrogenated in catalytic processes and are, therefore, a promising chemical hydrogen storage material. One of the promising candidates is the pair N ‐ethylcarbazole/perhydro‐ N ‐ethylcarbazole (NEC/H 12 ‐NEC). The dehydrogenation and possible side reactions on a Pt(111) surface are evaluated in unprecedented detail.