Catalytic Conversion of Cellulose to Ethylene Glycol over a Low‐Cost Binary Catalyst of Raney Ni and Tungstic Acid | Zendy

Tai Zhijun | Zendy; Zhang Junying | Zendy; Wang Aiqin | Zendy; Pang Jifeng | Zendy; Zheng Mingyuan | Zendy; Zhang Tao | Zendy

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Catalytic Conversion of Cellulose to Ethylene Glycol over a Low‐Cost Binary Catalyst of Raney Ni and Tungstic Acid

Author(s) -

Tai Zhijun,

Zhang Junying,

Wang Aiqin,

Pang Jifeng,

Zheng Mingyuan,

Zhang Tao

Publication year - 2013

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201200842

Subject(s) - raney nickel , catalysis , ethylene glycol , tungstic acid , cellulose , yield (engineering) , chemistry , hydrogenolysis , nuclear chemistry , inorganic chemistry , organic chemistry , materials science , metallurgy

Following our previous report on the selective transformation of cellulose to ethylene glycol (EG) over a binary catalyst composed of tungstic acid and Ru/C, we herein report a new low‐cost but more effective binary catalyst by using Raney nickel in place of Ru/C (Raney Ni+H 2 WO 4 ). In addition to tungstic acid, other W compounds were also investigated in combination with Raney Ni. The results showed that the EG yield depended on the W compound: H 4 SiW 12 O 40

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