Premium
Chemical Activation of a Mononuclear Non‐Porphyrinic Manganese Complex using Water as Oxygen Source for the Oxygen Atom Transfer Reaction
Author(s) -
El Kadiri Moulay Youness,
El Ghachtouli Sanae,
Guillot Régis,
Billon Laurianne,
Charlot MarieFrance,
Framery Eric,
Andrioletti Bruno,
Aukauloo Ally
Publication year - 2012
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201200440
Subject(s) - deprotonation , manganese , chemistry , oxygen , ligand (biochemistry) , catalysis , electron transfer , molecule , photochemistry , atom (system on chip) , oxygen atom , combinatorial chemistry , inorganic chemistry , organic chemistry , computer science , ion , biochemistry , receptor , embedded system
Water, a powerful ally: A Mn III complex with an N 4 O‐coordinating ligand and a deprotonated water molecule as sixth ligand is chemically oxidized by a Ce IV one‐electron oxidant. The results indicate catalytic oxygen atom transfer to alkenes, with the oxygen atom originating from a water molecule. These findings demonstrate the possibility of using water as oxygen source to perform the oxidation of organic substrates.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom