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Chemical Activation of a Mononuclear Non‐Porphyrinic Manganese Complex using Water as Oxygen Source for the Oxygen Atom Transfer Reaction
Author(s) -
El Kadiri Moulay Youness,
El Ghachtouli Sanae,
Guillot Régis,
Billon Laurianne,
Charlot MarieFrance,
Framery Eric,
Andrioletti Bruno,
Aukauloo Ally
Publication year - 2012
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201200440
Subject(s) - deprotonation , manganese , chemistry , oxygen , ligand (biochemistry) , catalysis , electron transfer , molecule , photochemistry , atom (system on chip) , oxygen atom , combinatorial chemistry , inorganic chemistry , organic chemistry , computer science , ion , biochemistry , receptor , embedded system
Water, a powerful ally: A Mn III complex with an N 4 O‐coordinating ligand and a deprotonated water molecule as sixth ligand is chemically oxidized by a Ce IV one‐electron oxidant. The results indicate catalytic oxygen atom transfer to alkenes, with the oxygen atom originating from a water molecule. These findings demonstrate the possibility of using water as oxygen source to perform the oxidation of organic substrates.