Ruthenium‐Catalyzed Conversion of Levulinic Acid to Pyrrolidines by Reductive Amination | Zendy

Huang YaoBing | Zendy; Dai JianJun | Zendy; Deng XiaoJian | Zendy; Qu YanChao | Zendy; Guo QingXiang | Zendy; Fu Yao | Zendy

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Ruthenium‐Catalyzed Conversion of Levulinic Acid to Pyrrolidines by Reductive Amination

Author(s) -

Huang YaoBing,

Dai JianJun,

Deng XiaoJian,

Qu YanChao,

Guo QingXiang,

Fu Yao

Publication year - 2011

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201100344

Subject(s) - levulinic acid , ruthenium , reductive amination , formic acid , catalysis , chemistry , amination , organic chemistry , decomposition , amine gas treating , aqueous solution , combinatorial chemistry

Combo deal: An aqueous solution of levulinic acid (LA) and formic acid (FA) derived from biomass‐based carbohydrates can be converted efficiently to pyrrolidines via a ruthenium catalyst without need for an energy‐intensive separation of LA or an external H 2 source. The ruthenium catalyst combines two processes: decomposition of FA to H 2 and reductive amination of LA with an amine.

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