Ru II ‐Mediated Hydrogen Transfer from Aqueous Glycerol to CO 2 : From Waste to Value‐Added Products | Zendy

Dibenedetto Angela | Zendy; Stufano Paolo | Zendy; Nocito Francesco | Zendy; Aresta Michele | Zendy

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Ru II ‐Mediated Hydrogen Transfer from Aqueous Glycerol to CO 2 : From Waste to Value‐Added Products

Author(s) -

Dibenedetto Angela,

Stufano Paolo,

Nocito Francesco,

Aresta Michele

Publication year - 2011

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201000434

Subject(s) - glycerol , formic acid , aqueous solution , chemistry , glycolic acid , catalysis , hydrogen , transfer hydrogenation , inorganic chemistry , nuclear chemistry , organic chemistry , ruthenium , lactic acid , biology , bacteria , genetics

Aqueous glycerol was used as the hydrogen source for the reduction of CO 2 to the hydrogen carrier formic acid in the presence of the catalyst [RuCl 2 (PPh 3 ) 3 ]. All intermediates were identified and characterized. Glycerol was converted into glycolic acid, HOCH 2 COOH, that was identified by using 1 H and 13 C NMR spectroscopy.

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