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Reactive Adsorption of NO 2 at Ambient Conditions on Iron‐Containing Polymer‐Based Porous Carbons
Author(s) -
Bashkova Svetlana,
Bandosz Teresa J.
Publication year - 2011
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201000296
Subject(s) - adsorption , thermogravimetric analysis , scanning electron microscope , carbon fibers , inorganic chemistry , maleic acid , fourier transform infrared spectroscopy , chemistry , dispersion (optics) , transmission electron microscopy , nuclear chemistry , materials science , chemical engineering , polymer , organic chemistry , nanotechnology , copolymer , physics , optics , composite number , engineering , composite material
Adsorption of NO 2 and retention of NO (the product of NO 2 reduction by carbon) on iron‐containing materials prepared from polystyrenesulfonic acid‐ co ‐maleic acid iron salt were studied. The surface of the materials was characterized using nitrogen adsorption, XRD, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy‐dispersive X‐ray (EDX), and FTIR spectroscopy, and thermogravimetric analysis (TGA). The results showed the positive effects of the pore volume and well‐dispersed iron species (Fe 2 O 3 , FeSO 4 , and FeS) on the performance of carbons as NO 2 adsorbents at room temperature. The retention of NO 2 on the carbon surface takes place either through its reduction to NO by carbon and/or by Fe 2 O 3 , FeSO 4 , and FeS, or through its reaction with Fe 2 O 3 and/or Fe(OH) 3 , leading to the formation of Fe(NO 3 ) 3 . The retention of NO is enhanced on carbons containing iron in the form of α‐FeOOH, α‐Fe 2 O 3 , or γ‐FeOOH. The best performance was found on the carbon with α‐Fe 2 O 3 . Dispersion and the particle size of iron compounds on the carbon surface affect both the adsorption/reduction process of NO 2 and the retention process of NO.