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Recent Innovative Strategies for the Synthesis of Amines: From CN Bond Formation to CN Bond Activation
Author(s) -
Krüger Karolin,
Tillack Annegret,
Beller Matthias
Publication year - 2009
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.200900121
Subject(s) - amine gas treating , chemistry , amination , reagent , reactivity (psychology) , nucleophile , combinatorial chemistry , cyclic amines , organic chemistry , catalysis , medicine , alternative medicine , pathology
Reconsider the use of amines: A new trend for the synthesis of different amine derivatives is presented by using the inherent reactivity of an existing CN bond of simpler amines. Typical amination methods are based on the addition of the NH bond enabled through the nucleophilicity of the amine. Novel reactions using amines as reagent also concentrate on the use of the mentioned CN bond to activate the α‐carbon atom as reacting part of the amine.