A Direct Route to Bifunctional Aldehyde Derivatives via Self‐ and Cross‐Metathesis of Unsaturated Aldehydes | Zendy

Miao Xiaowei | Zendy; Fischmeister Cédric | Zendy; Bruneau Christian | Zendy; Dixneuf Pierre H. | Zendy

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A Direct Route to Bifunctional Aldehyde Derivatives via Self‐ and Cross‐Metathesis of Unsaturated Aldehydes

Author(s) -

Miao Xiaowei,

Fischmeister Cédric,

Bruneau Christian,

Dixneuf Pierre H.

Publication year - 2009

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.200900028

Subject(s) - acrylonitrile , aldehyde , acrolein , bifunctional , metathesis , chemistry , ruthenium , catalysis , organic chemistry , olefin fiber , olefin metathesis , formaldehyde , combinatorial chemistry , polymerization , copolymer , polymer

Ruthenium‐catalyzed self‐ and cross‐metathesis , with acrolein, acrylonitrile, acrylic acid and methylacrylate, of the bioresource undecylenic aldehyde leads to a variety of unsaturated ω‐functional aldehydes. Tandem olefin metathesis/hydrogenation catalytic reactions afford saturated C 20 and C 12 diols in good yields.

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