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A Direct Route to Bifunctional Aldehyde Derivatives via Self‐ and Cross‐Metathesis of Unsaturated Aldehydes
Author(s) -
Miao Xiaowei,
Fischmeister Cédric,
Bruneau Christian,
Dixneuf Pierre H.
Publication year - 2009
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.200900028
Subject(s) - acrylonitrile , aldehyde , acrolein , bifunctional , metathesis , chemistry , ruthenium , catalysis , organic chemistry , olefin fiber , olefin metathesis , formaldehyde , combinatorial chemistry , polymerization , copolymer , polymer
Ruthenium‐catalyzed self‐ and cross‐metathesis , with acrolein, acrylonitrile, acrylic acid and methylacrylate, of the bioresource undecylenic aldehyde leads to a variety of unsaturated ω‐functional aldehydes. Tandem olefin metathesis/hydrogenation catalytic reactions afford saturated C 20 and C 12 diols in good yields.