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N ‐Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles
Author(s) -
Ishida Tamao,
Haruta Masatake
Publication year - 2009
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.200800260
Subject(s) - formylation , methyl formate , formamide , methanol , chemistry , colloidal gold , selectivity , formate , catalysis , molecular oxygen , nanoparticle , organic chemistry , photochemistry , combinatorial chemistry , nanotechnology , materials science
Dress code: formyl . Gold nanoparticles supported on NiO catalyze the one‐pot N ‐formylation of amines with methanol and molecular oxygen to produce formamide at a selectivity of 90 %. This process generates methyl formate in situ, followed by reaction with amines.