Catalytic Synthesis of Neutral H 2 O 2  Solutions from O 2  and H 2  by a Fuel Cell Reaction | Zendy

Yamanaka Ichiro | Zendy; Tazawa Satoshi | Zendy; Murayama Toru | Zendy; Ichihashi Ryo | Zendy; Hanaizumi Noriko | Zendy

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Catalytic Synthesis of Neutral H 2 O 2 Solutions from O 2 and H 2 by a Fuel Cell Reaction

Author(s) -

Yamanaka Ichiro,

Tazawa Satoshi,

Murayama Toru,

Ichihashi Ryo,

Hanaizumi Noriko

Publication year - 2008

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.200800176

Subject(s) - catalysis , cathode , fuel cells , tetraphenylporphyrin , hydrogen peroxide , carbon fibers , chemistry , electrode , electrochemistry , inorganic chemistry , materials science , chemical engineering , photochemistry , organic chemistry , porphyrin , composite number , engineering , composite material

Peroxide power : Neutral solutions of H 2 O 2 can be produced directly and safely from O 2 and H 2 by using a fuel cell reaction. The most active and efficient cathode is a vapour‐grown carbon fibre (VGCF) electrode coated with Co‐tetraphenylporphyrin (0.05 wt %) on VGCF (2 mg cm −2 ). A maximum concentration of 13.5 wt % (4.0 M ) H 2 O 2 is obtained under optimized conditions at 278 K.

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