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The Double Salts Cd(C 6 H 5 COO) 2 · CdCl 2 and Cd(C 6 H 5 COO) 2 · CdBr 2
Author(s) -
Balarew Christo,
Stefanova Rumiana
Publication year - 1996
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170310117
Subject(s) - chemistry , crystal structure , crystallography , ion , chemical composition , double salt , inorganic chemistry , stereochemistry , organic chemistry
The systems Cd(C 6 H 5 COO) 2 CdCl 2 H 2 O and Cd(C 6 H 5 COO) 2 CdBr 2 H 2 O have been studied at 25 °C. Formation of the double salts Cd(C 6 H 5 COO) 2 · CdCl 2 and Cd(C 6 H 5 COO) 2 · CdBr 2 (1:1:0) has been established and their chemical individuality has been confirmed by chemical, X‐ray, and DT‐analyses. Proceeding from data on the structure of Cd(C 6 H 5 COO) 2 · 2 H 2 O and the composition of the 1:1:0 double salts as well as using Pauling's rules for the most probable spacial disposition of the ions, the crystal structure type of the double salts obtained are predicted.