Premium
Synthesis and Structure Study of the Complex [Cu 2 ( μ –C 2 O 4 ) (C 10 H 8 N 2 ) 2 (H 2 O) 2 ] (C 6 H 4 COSO 2 N) 2 Crystal Structure Containing Cu (II) Bipy Oxalato and Saccharin
Author(s) -
Jianmin Li,
Jingzhen Sun,
Pengcheng Chen,
Xintao Wu
Publication year - 1995
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170300313
Subject(s) - monoclinic crystal system , crystallography , crystal structure , chemistry , copper , oxalate , ion , molecule , carboxylate , group (periodic table) , crystal (programming language) , x ray crystallography , stereochemistry , inorganic chemistry , diffraction , physics , organic chemistry , optics , computer science , programming language
The title compound has been synthesized and its crystal structure determined at room temperature. MW = 927.86, monoclinic, space group P2 1 / c , Z = 2, a = 9.283(1) Å, b = 16.239(2) Å, c = 12.209(1) Å, β = 99.848(9)°. The crystal structure consists of repeated [Cu 2 (μ–C 2 O 4 )(C 10 H 8 N 2 ) 2 · (H 2 O) 2 ] 2 cations and non‐coordinated saccharin anions. Each copper ion is in a square pyrimidal environment with two oxalate oxygen and two bipyridine nitrogen atoms as a base and one water molecule at the apex. The two copper ions are bridged by oxalato and the distance is 5.138 Å.