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Coloured zirconia
Author(s) -
Römer H.,
Luther K.D.,
Assmus W.
Publication year - 1994
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170290604
Subject(s) - yttrium , valence (chemistry) , yttria stabilized zirconia , cubic zirconia , zirconium , oxide , crystal structure , materials science , ion , lattice (music) , crystal (programming language) , crystallography , local symmetry , inorganic chemistry , mineralogy , chemistry , ceramic , metallurgy , organic chemistry , physics , quantum mechanics , computer science , acoustics , programming language
This paper deals with the growth of coloured zirconium oxide crystals, cubic stabilized with yttrium oxide. The host material–zirconia–is colourless. To generate colourations minor concentrations of 3d‐ and 4f‐elements are incorporated into the lattice. The resulting colours are dependent on the ions' valence and the local crystal symmetry. Both, the possibility to change the ions' valence by heat treatment, and the possibility to change the local crystal symmetry by alteration of the starting yttria concentration, are discussed in the following.