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Structure Characterization of EDTA Transition Metal Complexes (II) Study on Ba[Co(HEDTA)H 2 O] 2 · 4H 2 O
Author(s) -
Yugeng Zhang,
Jianmin Li,
Jifa Fan
Publication year - 1992
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170270214
Subject(s) - chemistry , transition metal , crystal structure , ligand field theory , crystallography , ligand (biochemistry) , inorganic chemistry , ion , metal , characterization (materials science) , crystal (programming language) , materials science , nanotechnology , receptor , organic chemistry , catalysis , biochemistry , computer science , programming language
The d‐d transition spectrum of Ba[Co(HEDTA)H 2 O] 2 · 4H 2 O crystal was measured at room temperature and experimental results are explained quantitativley by using the ligand field theory and the radial wave function of non‐free Co(II) ion. The crystal structures and the electronic structures of M/Co‐EDTA (M=Ba, Sr, Ca, Mg) complexes are also discussed.