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Synthesis and Structural Characterisation of 2‐Aminoacetophenonesalicylaldazine Complexes of Some Bivalent Transition Metal Ions
Author(s) -
Singh B.,
Singh U. R.
Publication year - 1991
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170260813
Subject(s) - bivalent (engine) , orthorhombic crystal system , chemistry , crystallography , azine , transition metal , metal , metal ions in aqueous solution , ion , inorganic chemistry , crystal structure , medicinal chemistry , organic chemistry , catalysis
Metal(II) complexes M(aas) 2 [M = Mn. Co, Ni, Cu and Zn, Haas = 2‐aminoacetophenonesalicylaldazine] have been prepared and characterized. Magnetic and spectral data such as electronic, ESR, and IR are used to establish the stereochemistry and mode of bonding of azine in the complexes. X‐ray diffraction study suggests orthorhombic unit lattice for Co(aas) 2 , Ni(aas) 2 , Cu(aas) 2 and Zn(aas) 2 complexes.