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Crystal and Molecular Structure of mer‐Co(4‐CH 3 C 5 H 4 N) 3 (N 3 ) 3
Author(s) -
Mautner F. A.
Publication year - 1991
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170260713
Subject(s) - monoclinic crystal system , crystal structure , crystallography , molecule , chemistry , azide , x ray crystallography , crystal (programming language) , stereochemistry , pyridine , group (periodic table) , cobalt , inorganic compound , inorganic chemistry , physics , medicinal chemistry , diffraction , programming language , computer science , organic chemistry , optics
The crystal structure of mer‐Co(4‐CH 3 C 5 H 4 N) 3 (N 3 ) 3 has been determined by single crystal X‐ray methods at 300 K. The compound crystallizes in the monoclinic space group C 2/c, a = 19.087(6), b = 16.769(4), c = 15.845(4) Å, β = 119.04(2)°, V = 4434(2) Å 3 , M r = 464.42. Z = 8, D x = 1.391 Mgm −3 , F (000) = 1920, λ (MoKα) = 0.71069 Å, μ = 0.802 mm −1 . The cobalt(III) ions are octahedrally coordinated to three azide groups and to three 4‐methyl‐pyridine molecules to form isolated coordination polyhedra.