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The d‐d Transition Spectra of Copper (II) Complexes in Different Coordination Environment. Study on Cu(TTA) 2 and Cu 2 (sacch) 4 (Im) 4
Author(s) -
Jianmin Li,
Yugeng Zhang
Publication year - 1991
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170260316
Subject(s) - copper , spectral line , chemistry , transition metal , crystallography , crystal (programming language) , coordination complex , physics , catalysis , organic chemistry , astronomy , metal , computer science , programming language
The d‐d transition spectra of Cu(TTA) 2 and Cu 2 (sacch) 4 (Im) 4 complexes crystals have been determined. Using the crystal structure data, their d‐d transition energy levels are calculated by the program which we used for the calculation of field theory. The calculated values are in good accordance with the experimental results. Compared to the copper(II) complexes in various coordination environments, their d‐d transition spectra have an evident difference.