On the chemical vapour transport of nickel titanate with selenium tetrachloride | Zendy

Bieger W. | Zendy; Piekarczyk W. | Zendy; Krabbes G. | Zendy; Stöver G. | Zendy; van Hai Ngyen | Zendy

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On the chemical vapour transport of nickel titanate with selenium tetrachloride

Author(s) -

Bieger W.,

Piekarczyk W.,

Krabbes G.,

Stöver G.,

van Hai Ngyen

Publication year - 1990

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.2170250406

Subject(s) - non blocking i/o , nickel , chemical vapor deposition , selenium , deposition (geology) , chemistry , titanate , tetrachloride , inorganic chemistry , materials science , organic chemistry , paleontology , ceramic , sediment , tin , biology , catalysis

The chemical vapour transport (CVT) of NiTiO 3 with SeCl 4 is reported. In addition to small NiTiO 3 crystals a more or less quantity of solid NiCl 2 is deposited in the deposition zone. At higher temperature gradients the solid which is deposited besides NiCl 2 is NiO. The transport behaviour is satisfactory explained using two thermodynamical models: the model of connected equilibrium states and the four‐stage model.

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