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Oxidation of tetracyanonickellate (II) in the presence of organic cation
Author(s) -
Oza A. T.
Publication year - 1989
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170240715
Subject(s) - redox , chemistry , infrared , absorption (acoustics) , absorption spectroscopy , infrared spectroscopy , inorganic chemistry , materials science , organic chemistry , physics , optics , composite material , quantum mechanics
Abstract A new material (TMPD) 2 Ni(CN) 4 I 0.5 · H 2 O has been prepared (TMPD = N,N,N′,N′‐tetramethyl‐p‐phenylenediamine). The solution and mull absorption spectra in the infrared range indicate the presence of the redox process TMPD + ⇌ TMPD 2+ and tetracyanonickellate (IV) units.