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Crystal and molecular structure of tetrachloro tetraaquo‐(1,8,10,17‐tetraazacyclooctadecane‐9,10‐dithione) dicopper (II)
Author(s) -
Mishra Lallan,
Pandey A. K.
Publication year - 1989
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170240327
Subject(s) - orthorhombic crystal system , crystallography , thiourea , paramagnetism , crystal structure , copper , chemistry , elemental analysis , infrared spectroscopy , molecule , inorganic chemistry , organic chemistry , physics , quantum mechanics
Tetradentate bioactive macrocyclic thiourea 1,8,10,17‐tetraazacyclooctadecane‐9,18‐dithione(L) has been complexed with copper chloride dihydrate yielding bluish green coloured paramagnetic complex of orthorhombic geometry. The composition and tentative environment around Cu(II) is assigned on the basis of elemental analysis, IR, ESR spectra, X‐ray diffraction and magnetic studies.