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The crystal structure of zinc azide · 2‐methylpyridine at 98 K
Author(s) -
Mautner Franz A.,
Kratky Christoph
Publication year - 1988
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170231212
Subject(s) - azide , zinc , chemistry , crystallography , pyridine , adduct , crystal structure , trigonal bipyramidal molecular geometry , crystal (programming language) , atom (system on chip) , stereochemistry , medicinal chemistry , organic chemistry , computer science , programming language , embedded system
The crystal structure of the title compound has been determined by single crystal X‐ray diffraction methods at 98 K. Zinc azide · 2‐methyl pyridine crystallizes in the space group P 1 with a = 6.028(2) Å, b = 7.610(3) Å, c = 10.052(4) Å, α = 92.81(3)°, β = 101.08(2)·, γ = 94.64(3)° and Z = 2. Least‐squares refinement gave an R value of R w = 0.039 for 2096 observed reflections. Each zinc atom is surrounded by four nitrogen atoms of different azide groups and one nitrogen atom of the pyridine adduct in a distorted trigonal bipyramidal fashion. The ZnN 5 ‐polyhedra share common edges to form chains along the crystallographic a ‐axis.
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