Diamagnetism and some peculiarities of interatomic interactions in Cu 2 Sb | Zendy

Vitkina Ts. Z. | Zendy; Zhigadlo N. D. | Zendy; Ryzhkovskii V. M. | Zendy

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Diamagnetism and some peculiarities of interatomic interactions in Cu 2 Sb

Author(s) -

Vitkina Ts. Z.,

Zhigadlo N. D.,

Ryzhkovskii V. M.

Publication year - 1988

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.2170230720

Subject(s) - diamagnetism , covalent bond , magnetic susceptibility , electrical resistivity and conductivity , chemistry , condensed matter physics , materials science , crystallography , magnetic field , physics , organic chemistry , quantum mechanics

Results are reported for magnetic susceptibility measurements of high purity Cu 2 Sb which characterize it as a diamagnetic. The observed anomalies of magnetic susceptibility, electrical resistivity and linear expansion coefficient in the neighbourhood of 370 K verify the existence of a phase transition of nonmagnetic origin in this temperature range. The analysis of the peculiarities of interatomic interaction in Cu 2 Sb indicates the covalent character of the bonding. The value of the strength of the CuCu and CuSb bond is evaluated. It is shown that the CuCu bond in the Cu 2 Sb compound is the most strong one.

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