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Combined investigations of NiAl alloys by means of X‐ray photoelectron spectroscopy, compton gamma scattering and positron annihilation
Author(s) -
Hoppe W.,
Marx U.,
Dlubek G.,
Brümmer O.
Publication year - 1988
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170230320
Subject(s) - nial , spectral line , compton scattering , atomic physics , x ray photoelectron spectroscopy , materials science , positron , charge (physics) , electron , annihilation , nuclear physics , physics , alloy , intermetallic , nuclear magnetic resonance , metallurgy , quantum mechanics , astronomy
Abstract The results of measurements of Compton profiles, photoelectron spectra, positron annihilation curves, and lifetime spectra of several NiAl alloys are discussed in terms of bonding and stability in transition metal aluminides. The interpretation of experimental Compton profiles suggests a transfer of nearly‐free electrons from Al sites to more localized d‐like states on Ni‐sites. The transfer increases with Al contents up to 50 atomic percent. From X‐ray photoelectron spectra in the case of Al‐rich alloys a different behaviour follows. The results support a model established by Wenger. Following this in the composition range above 50 percent Al no further charge is transferred to Ni cells. The Ni d states seem to be occupied in the Al‐rich alloys. A preferential annihilation of positrons in Ni cells is though to have its origin in the enhanced negative charge of these cells caused by charge transfer.