The crystal structure of nematogenic 2‐bromo‐1,4‐phenylenediyl bis(trans‐4‐n‐propylcyclohexanoate) — a special kind of disorder | Zendy

Hartung H. | Zendy; Winter G. | Zendy

Premium

The crystal structure of nematogenic 2‐bromo‐1,4‐phenylenediyl bis(trans‐4‐n‐propylcyclohexanoate) — a special kind of disorder

Author(s) -

Hartung H.,

Winter G.

Publication year - 1987

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.2170220220

Subject(s) - triclinic crystal system , crystal structure , molecule , crystallography , chemistry , stereochemistry , materials science , organic chemistry

The title compound with the formula C 3 H 7 –C 6 H 10 –COO–C 6 H 3 BrOOCC 6 H 10 C 3 H 7 (BPBPC) crystallizes in a triclinic unit cell with dimensions a = 5.822(2), b = 8.732(3), c = 13.016(5) Å, α = 94.42(3)°, β = 93.47(3)°, γ = 104.85(2)° containing one molecule. The structure has been solved by heavy atom method and refined to R = 0.083. The BPBPC molecules adopt an optimum stretched form and exhibit pseudo‐centrosymmetry in consequence of a special kind of disorder within the crystal lattice.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research