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Growth of bis‐dimethylglyoximate Co (III). Single crystals
Author(s) -
GarciaRuiz J. M.,
Lopez Martinez C.,
MartinVivaldi Cabellero J. L.
Publication year - 1985
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170201214
Subject(s) - monoclinic crystal system , crystallography , diffusion , materials science , orange (colour) , crystal growth , chemistry , czochralski method , analytical chemistry (journal) , crystal structure , chromatography , physics , thermodynamics , food science
Single crystals of bis‐dimethylglyoximate Co(III) up to 8 × 6 × 2 mm. in size have been grown by the first time, using diffusion method at room temperature. Optimum size and quality were obtained at p H = 6. These crystals are orange in colour and an X‐ray study shows it to be monoclinic, space group P 2 1 /n, with a = 8.432(4), b = 14.147(3), c = 13.746 (6) and β = 103.78(3)°. The effects of different experimental devices on the growth features are discussed.