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On the determination of kinetic data for the continuous crystallization of potassuim chloride
Author(s) -
Kodura J.,
Gramlich K.,
Karwoth R.
Publication year - 1985
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170200704
Subject(s) - crystallization , potassium , kinetic energy , chemistry , realization (probability) , chloride , salt (chemistry) , constant (computer programming) , inorganic chemistry , thermodynamics , analytical chemistry (journal) , chromatography , organic chemistry , physics , mathematics , computer science , quantum mechanics , statistics , programming language
A method for the determination of the kinetic constants and the realization of experiments for the bulk crystallization from solutions with particular reference to potassium chloride have been described. A new relation has been used for determining the kinetic constant, i, affording the advantage of being less sensitive to experimental errors. It can be regarded as fitting quite well with the data reported in the literature. A marked trend in the decrease in magnitude of the superscript, i , with increasing companion salt contents is noted. The value of i varies from 3.8 for technical potassium chloride to 2.0 for a fourcomponent solution.