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Crystal and molecular structure of Bis(N‐[pyrid‐2‐yl]‐1‐imino‐2‐carbethoxy‐3‐oxo‐butan‐2‐ido)‐palladium (II)
Author(s) -
Reck G.,
Bannier G.,
Heyn B.,
Jäger E.G.
Publication year - 1984
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170191219
Subject(s) - orthorhombic crystal system , palladium , crystal structure , chemistry , crystallography , lattice constant , coordination sphere , atom (system on chip) , molecule , diffraction , stereochemistry , catalysis , physics , organic chemistry , computer science , optics , embedded system
The crystal and molecular structure of the title compound has been determined by X‐ray diffraction techniques. It crystallizes in the orthorhombic space group Pbca with 4 formula units C 24 H 26 N 4 O 6 Pd in the unit cell. The lattice constants are a = 17.259, b = 19.070, and c = 7.480 Å. The structure was solved by the heavy atom technique and refined by least‐squares calculations to the conventional R = 0.057. The coordination sphere of palladium as well as the molecular geometry of the ligands are discussed in the paper.