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Results of crystal growth of bismuth‐antimony alloys (Bi 100– x Sb x ) in a microgravity environment
Author(s) -
Schneider G.,
Herrmann R.,
Krüger H.,
Rudolph P.,
Kuhl R.,
Röstel R.
Publication year - 1983
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.2170181002
Subject(s) - ampoule , crystal growth , antimony , bismuth , materials science , crystal (programming language) , diffusion , mass transfer , homogeneous , convection , crystallography , chemical physics , chemistry , thermodynamics , composite material , metallurgy , physics , chromatography , computer science , programming language
Results of two experiments are presented for growth of crystals from (Bi 100– x Sb x ) alloys in a microgravity environment. In the growth experiments different variants of the Bridgman technique were used. It was shown that in crystal growth from the melt in closed ampoules under microgravity conditions convection can be prevented completely. Therefore it is possible to grow crystals from melts of some components under diffusion controlled conditions of mass transfer. In microgravity a reduced interaction between the melt and the confining walls was observed even if they have large contact with each other. The investigation of surface morphology corroborated the importance of surface effects for crystal growth from the melt under microgravity conditions. Measurements of electronic properties of crystals grown in microgravity showed a good quality in comparison to earth grown crystals. Because under microgravity conditions in closed ampoules the diffusion controlled mass transfer can be realized and the interaction between the melt and confining wall is reduced, homogeneous crystals with high perfection can be grown melts of some components.