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Effects of Rare Earth Elements and Nitrogen Co‐Doped on the Photocatalytic Performance of TiO 2
Author(s) -
Bao Ruiyu,
Yu Yanmin,
Chen Huiying,
Wang Wenzhong,
Xia Jianxin,
Li Hua
Publication year - 2018
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.201700138
Subject(s) - photocatalysis , cerium , x ray photoelectron spectroscopy , praseodymium , materials science , lanthanum , lutetium , scanning electron microscope , nuclear chemistry , calcination , diffuse reflectance infrared fourier transform , samarium , visible spectrum , lanthanide , analytical chemistry (journal) , inorganic chemistry , chemistry , ion , yttrium , oxide , chemical engineering , catalysis , chromatography , metallurgy , biochemistry , optoelectronics , engineering , composite material , organic chemistry
Titanium dioxide (TiO 2 ), which is codoped with nine different rare earth mental ions (RE 3+ = lanthanum (La 3+ ), cerium (Ce 3+ ), praseodymium (Pr 3+ ), neodymium (Nd 3+ ), samarium (Sm 3+ ), gadolinium (Gd 3+ ), erbium (Er 3+ ), ytterbium (Yb 3+ ), lutetium (Lu 3+ )) and nitrogen (N), are synthesized by non‐hydrolytic sol‐gel method under different calcination temperatures. The morphology, structure and performance of as‐prepared samples are characterized by X‐ray diffraction (XRD), scanning electron microscope (SEM), X‐ray photoelectron spectroscopy (XPS), UV‐vis diffuse reflectance spectroscopy (DRS) and ultraviolet‐visible absorption spectroscopy. The results indicat that co‐doping can inhibit the particles growth significantly and extend light‐absorption to the visible region. Nd/N and Pr/N co‐doped TiO 2 (calcining temperature at 380 °C) exhibit superior photocatalytic activity toward methyl orange (MO) degradation under visible light irradiation for 150 min, the degradation rate of MO solution are approximately 91 and 89% respectively. By comparison, the degradation rate are only 43 and 7% for the N‐TiO 2 and pure TiO 2 respectively.