Premium
Second harmonic generation properties of Ca 3 (O 3 C 3 N 3 ) 2 ‐Sr 3 (O 3 C 3 N 3 ) 2 solid solutions
Author(s) -
Kalmutzki Markus,
Wang Xiao,
Meixner Alfred J.,
Meyer HansJürgen
Publication year - 2016
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.201600029
Subject(s) - second harmonic generation , chemistry , exothermic reaction , metathesis , phase diagram , solid solution , crystallography , inorganic chemistry , analytical chemistry (journal) , phase (matter) , physics , laser , organic chemistry , chromatography , optics , polymerization , polymer
Solid solutions of the second harmonic generation (SHG) materials Ca 3 (O 3 C 3 N 3 ) 2 (CCY) and Sr 3 (O 3 C 3 N 3 ) 2 (SCY) were prepared via exothermic solid state metathesis reactions from appropriate amounts of the corresponding metal chlorides and potassium cyanate at 525 °C. The change in SHG intensity caused by the successive cation substitution is reported. Differential thermal analyses are used to explore the SCY–K(OCN) phase diagram as a medium for the growth of SCY crystals.