Second harmonic generation properties of Ca 3 (O 3 C 3 N 3 ) 2  ‐Sr 3 (O 3 C 3 N 3 ) 2  solid solutions | Zendy

Kalmutzki Markus | Zendy; Wang Xiao | Zendy; Meixner Alfred J. | Zendy; Meyer HansJürgen | Zendy

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Second harmonic generation properties of Ca 3 (O 3 C 3 N 3 ) 2 ‐Sr 3 (O 3 C 3 N 3 ) 2 solid solutions

Author(s) -

Kalmutzki Markus,

Wang Xiao,

Meixner Alfred J.,

Meyer HansJürgen

Publication year - 2016

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.201600029

Subject(s) - second harmonic generation , chemistry , exothermic reaction , metathesis , phase diagram , solid solution , crystallography , inorganic chemistry , analytical chemistry (journal) , phase (matter) , physics , laser , organic chemistry , chromatography , optics , polymerization , polymer

Solid solutions of the second harmonic generation (SHG) materials Ca 3 (O 3 C 3 N 3 ) 2 (CCY) and Sr 3 (O 3 C 3 N 3 ) 2 (SCY) were prepared via exothermic solid state metathesis reactions from appropriate amounts of the corresponding metal chlorides and potassium cyanate at 525 °C. The change in SHG intensity caused by the successive cation substitution is reported. Differential thermal analyses are used to explore the SCY–K(OCN) phase diagram as a medium for the growth of SCY crystals.

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