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Synthesis by precipitation method and investigation of SnO 2 nanoparticles
Author(s) -
Nejati K.
Publication year - 2012
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.201100633
Subject(s) - tin dioxide , rutile , transmission electron microscopy , nanoparticle , particle size , annealing (glass) , tetragonal crystal system , calcination , fourier transform infrared spectroscopy , analytical chemistry (journal) , materials science , tin , photoluminescence , precipitation , spectroscopy , chemical engineering , infrared spectroscopy , chemistry , nanotechnology , crystallography , crystal structure , chromatography , metallurgy , organic chemistry , catalysis , physics , optoelectronics , quantum mechanics , meteorology , engineering
In this paper the synthesis of SnO 2 nanoparticles with average particle size up to about 70 nm using SnCl 2 2H 2 O and NH 4 OH in 1‐botanol solution by the precipitation method is reported and the inhibition of sodium dodecyl sulphate (SDS) on the SnO 2 particle growth is investigated by soaking SnO 2 precursor in the SDS solution for 24 h. The as‐prepared SnO 2 and SDS modified‐SnO 2 powders, then, were calcined at different temperatures and the X‐ray powder diffraction (XRD) and Fourier transform infrared spectroscopy (FT‐IR) were used to characterize the output samples. The XRD results reveal that the structure of tin‐dioxide is tetragonal rutile and the as‐prepared SnO 2 nanoparticles grow with increasing the annealing temperature, while the SDS treatment prevents the particle growth under the same condition. Furthermore, the FT‐IR results indicate the formation of tin‐hydroxyl group which are then converted into tin‐dioxide with heat treatment. Further characterization of the samples by the transmission electron microscopy (TEM) and the photoluminescence (PL) spectroscopy was carried out. The room temperature PL spectra of SnO 2 exhibits broad and strong peak attributed to the surface defects such as oxygen vacancies and intensity of which decreases with the increase in particle size. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)