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A controllable ionic liquid‐assisted hydrothermal route to prepare CoCO 3 crystals and their conversion to porous Co 3 O 4
Author(s) -
Li Haobo,
Duan Xiaochuan,
Ma Jianmin,
Zheng Wenjun
Publication year - 2012
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.201100290
Subject(s) - coco , hydrothermal circulation , ionic liquid , chemical engineering , porosity , ionic bonding , hydrothermal synthesis , materials science , morphology (biology) , porous medium , chemistry , nanotechnology , ion , catalysis , organic chemistry , computer science , engineering , artificial intelligence , biology , genetics
In this work, we have synthesized CoCO 3 microaggregation, microcubes and nanoplates by an ionic liquid‐assisted hydrothermal method. The morphologies of the CoCO 3 crystals depend on the concentration of the ionic liquid and the reaction temperature. Moreover, the as‐prepared CoCO 3 crystals can serve as a useful precursor to obtain porous Co 3 O 4 particles with similar morphology by means of calcinations. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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