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Synthesis, structure and electrochemical performance of cobaltite‐based composite cathodes for IT‐SOFC
Author(s) -
Cesário M. R.,
Macedo D. A.,
Martinelli A. E.,
Nascimento R. M.,
Barros B. S.,
Melo D. M. A.
Publication year - 2012
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.201100028
Subject(s) - materials science , cathode , composite number , cobaltite , scanning electron microscope , electrochemistry , chemical engineering , dielectric spectroscopy , oxide , combustion , perovskite (structure) , composite material , electrode , metallurgy , chemistry , organic chemistry , engineering
The development of novel and high‐performance cathodes is a critical issue to be addressed in order to reduce Solid Oxide Fuel Cells (SOFCs) operation temperature to the 600‐800 °C range or less. The performance of CeO 2 ‐based composite cathodes is very attractive to such operational temperatures. In this work, La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 (LSCF) and Ce 0.8 Sm 0.2 O 1.9 (SDC) powders were synthesized by different synthesis methods and mechanically mixed to prepare LSCF‐SDC composite cathodes. Screen‐printed LSCF‐SDC/CGO/LSCF‐SDC symmetrical cells were sintered at 1150 °C for 4 h and characterized by electrochemical impedance spectroscopy in static air. X‐ray diffraction and scanning electron microscopy were employed to characterize the powders. Area specific resistance values of 0.72 and 2.77 Ω cm 2 at 800 °C were found for composite cathodes containing SDC powder synthesized by modified Pechini and microwave‐assisted combustion methods, respectively. Furthermore, the activation energy of the composite cathode containing SDC derived from modified Pechini method is 1.18 eV, i.e., much lower than 1.73 eV, value determined for LSCF with SDC from microwave‐combustion method.