Syntheses and crystal structures of two polymorphs of three‐dimensional silver (I) 5‐(3‐aminophenyl)tetrazolates | Zendy

Kou JunFeng | Zendy; Zhu Yu | Zendy; Yang Guang | Zendy

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Syntheses and crystal structures of two polymorphs of three‐dimensional silver (I) 5‐(3‐aminophenyl)tetrazolates

Author(s) -

Kou JunFeng,

Zhu Yu,

Yang Guang

Publication year - 2009

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200900071

Subject(s) - crystallography , hydrothermal circulation , single crystal , chemistry , tetrazole , crystal structure , diffraction , ammonia , elemental analysis , hydrothermal synthesis , powder diffraction , stereochemistry , inorganic chemistry , organic chemistry , geology , physics , seismology , optics

Two polymorphs of silver 5‐(3‐aminophenyl)tetrazolates – α‐ and β‐Ag(amphttz) have been obtained by the reaction of amphttzH with AgNO 3 in presence of ammonia either in ambient condition or under the hydrothermal condition, respectively (amphttzH = 5‐(3‐aminophenyl)tetrazole). Both of the two phases of Ag(amphttz) were characterized by elemental analyses, IR spectra and single‐crystal X‐ray diffraction. X‐ray analysis shows α‐, β‐phases crystallize in P ‐1 with a = 8.551 (2) Å, b = 8.720(2) Å, c = 11.173(2) Å, α = 98.15(3)°, β = 90.95(3)°, γ = 95.45(3)° and C 2/ c with a = 13.542(3) Å, b = 10.135(2) Å, c = 12.610(3) Å, β = 113.58(3)°, respectively. The two polymorphs exhibit different 3D structures. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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