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Synthesis of a two‐dimensional porous framework based on symmetrical organic ligand and linking metal ion
Author(s) -
Wu Jian
Publication year - 2009
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200800566
Subject(s) - carboxylate , chemistry , ligand (biochemistry) , acceptor , molecule , metal organic framework , metal , salt (chemistry) , copper , bridging ligand , polymer , polymer chemistry , porosity , ion , crystallography , inorganic chemistry , stereochemistry , organic chemistry , adsorption , receptor , biochemistry , physics , condensed matter physics
Reaction of a pyridinecarboxylate ligand with copper salt affords a novel coordinative polymer [Cu(bpdc)(H 2 O) 2 ·2H 2 O]n (bpdc=.2,2'‐bipyridyl‐3,3'‐dicarboxylate). It has 2‐D (4,4) layered network extended by the tetradentate bridging ligands, further interestingly, the coordinative and lattice water molecules acting as donor and acceptor linking the uncoordinated carboxylate groups into a inorganic (6,3) network. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)