Synthesis of a two‐dimensional porous framework based on symmetrical organic ligand and linking metal ion | Zendy

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Synthesis of a two‐dimensional porous framework based on symmetrical organic ligand and linking metal ion

Author(s) -

Wu Jian

Publication year - 2009

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200800566

Subject(s) - carboxylate , chemistry , ligand (biochemistry) , acceptor , molecule , metal organic framework , metal , salt (chemistry) , copper , bridging ligand , polymer , polymer chemistry , porosity , ion , crystallography , inorganic chemistry , stereochemistry , organic chemistry , adsorption , receptor , biochemistry , physics , condensed matter physics

Reaction of a pyridinecarboxylate ligand with copper salt affords a novel coordinative polymer [Cu(bpdc)(H 2 O) 2 ·2H 2 O]n (bpdc=.2,2'‐bipyridyl‐3,3'‐dicarboxylate). It has 2‐D (4,4) layered network extended by the tetradentate bridging ligands, further interestingly, the coordinative and lattice water molecules acting as donor and acceptor linking the uncoordinated carboxylate groups into a inorganic (6,3) network. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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