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A novel porous network with interpenetrating topology
Author(s) -
Wu Jian
Publication year - 2009
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200800308
Subject(s) - diamondoid , tetragonal crystal system , propane , topology (electrical circuits) , molecule , infrared spectroscopy , ligand (biochemistry) , crystallography , polymer , ion , single crystal , chemistry , porosity , crystal structure , materials science , organic chemistry , combinatorics , mathematics , receptor , biochemistry
Abstract A new Co II coordination polymer with complicated topology, namely [Co(bpp) 2 Cl 2 ]n (1) (bpp=1,3‐bis(4‐pyridyl)propane), has been designed and synthesized based on flexible ligand under basic condition. The complex was characterized by single‐crystal X‐ray analysis and infrared spectroscopy. The Co II ions are linked into a 3D structure via bpp molecules. Four independent frameworks are related by translation along the c tetragonal axis in the usual interpenetration topology for diamondoid frames. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)