Synthesis, characterization and crystal structure of a novel 2D Cu(I) complex with flexible ligand | Zendy

Liu Jianqiang | Zendy; Wang Yaoyu | Zendy; Zhang Weihong | Zendy; Jin Juncheng | Zendy; Zhang Mei | Zendy; Shi Qizhen | Zendy

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Synthesis, characterization and crystal structure of a novel 2D Cu(I) complex with flexible ligand

Author(s) -

Liu Jianqiang,

Wang Yaoyu,

Zhang Weihong,

Jin Juncheng,

Zhang Mei,

Shi Qizhen

Publication year - 2009

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200800198

Subject(s) - monoclinic crystal system , crystallography , molecule , ligand (biochemistry) , chemistry , crystal structure , hydrothermal circulation , ion , characterization (materials science) , methane , crystal (programming language) , group (periodic table) , single crystal , hydrogen bond , stereochemistry , materials science , nanotechnology , chemical engineering , organic chemistry , receptor , biochemistry , programming language , computer science , engineering

An exploration of the Cu(I)‐L system under hydrothermal conditions, has led to the isolation of a novel framework [Cu(I)(L)] n ( 1 ) (L = bis(3,3‐dimethyl‐4,4‐dihydro‐1H‐pyrazol‐4‐yl)methane). Single‐crystal X‐ray analysis reveals that it crystallizes in the monoclinic, space group C2/c, a = 19.781(4) Å, b =11.026(3) Å, c = 16.339(4) Å, β = 127.186(3)°. The Cu ions are linked into an extended rainbow‐like chain via L molecules. Further, these adjacent chains are united together through hydrogen‐bonded interaction to a 2D layer. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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