Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4'‐diazenediyldiphthalic acid ligand | Zendy

Lu Lu | Zendy; Wang Jun | Zendy; Bai JianWei | Zendy; Hou Yang | Zendy; Yang Bin | Zendy; Zhao BaoZhong | Zendy

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Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4'‐diazenediyldiphthalic acid ligand

Author(s) -

Lu Lu,

Wang Jun,

Bai JianWei,

Hou Yang,

Yang Bin,

Zhao BaoZhong

Publication year - 2008

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200800086

Subject(s) - triclinic crystal system , crystal structure , crystallography , chemistry , rectangle , ligand (biochemistry) , cadmium , ion , hydrothermal synthesis , hydrothermal circulation , honeycomb , stereochemistry , materials science , mathematics , geometry , biology , biochemistry , receptor , organic chemistry , composite material , paleontology

An exploration of the cadmium‐L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L) 0.5 (H 2 O) 3 ]} n ( 1 ) (H 4 L = 4,4'‐diazenediyldiphthalic acid). Single‐crystal X‐ray analysis reveals that it crystallizes in the triclinic space group P‐1. a = 5.746(3) Å, b =6.526(4) Å, c = 14.701(8) Å, α=92.348(8), β = 99.622(6), γ=106.877(7)°. The Cd II ions are linked into an extended 2‐D rectangle‐like structure via L ligands, which exhibits an attractive three‐connected honeycomb topological network. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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