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Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4'‐diazenediyldiphthalic acid ligand
Author(s) -
Lu Lu,
Wang Jun,
Bai JianWei,
Hou Yang,
Yang Bin,
Zhao BaoZhong
Publication year - 2008
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200800086
Subject(s) - triclinic crystal system , crystal structure , crystallography , chemistry , rectangle , ligand (biochemistry) , cadmium , ion , hydrothermal synthesis , hydrothermal circulation , honeycomb , stereochemistry , materials science , mathematics , geometry , biology , biochemistry , receptor , organic chemistry , composite material , paleontology
An exploration of the cadmium‐L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L) 0.5 (H 2 O) 3 ]} n ( 1 ) (H 4 L = 4,4'‐diazenediyldiphthalic acid). Single‐crystal X‐ray analysis reveals that it crystallizes in the triclinic space group P‐1. a = 5.746(3) Å, b =6.526(4) Å, c = 14.701(8) Å, α=92.348(8), β = 99.622(6), γ=106.877(7)°. The Cd II ions are linked into an extended 2‐D rectangle‐like structure via L ligands, which exhibits an attractive three‐connected honeycomb topological network. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)