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Synthesis and crystal strcucture of two zinc inclusion complexes
Author(s) -
Han MinLe,
Mi LiWei,
Chen WeiHua
Publication year - 2008
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200711118
Subject(s) - sulfonate , chemistry , cationic polymerization , propane , hydrogen bond , naphthalene , molecule , crystal structure , crystallography , bipyridine , stereochemistry , medicinal chemistry , polymer chemistry , organic chemistry , sodium
X‐ray single crystals of these two inclusion complexes, [Zn(H 2 O) 4 L 2 ]·(4‐amino‐1‐naphthalene sulfonate) 2 (L = 1,3‐bis(4‐pyridyl) propane), 1 , and [Zn(H 2 O)(bipy) 2 ]·(4‐amino‐1‐naphthalene sulfonate)(NO 3 ) (bipy = 4,4'‐bipyridine), 2 were achieved by the reaction of Zn(NO 3 ) 2 and 4‐amino‐1‐naphthalene sulfonate to 1,3‐bis(4‐pyridyl) propane and 4,4'‐bipyridine, respectively. As inclusion complexes, the cationic components of 1 and 2 were formed by two infinite zigzag chains, while, 4‐amino‐1‐naphthalene sulfonate made up the anionic parts of these two complexes. Thus, the whole molecules of these two complexes are neuter. Numous hydrogen bonds could be found in these two inclusion complexes, which help them to form three‐dimensional solid‐state packing structure architectures. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)